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A N2-bridged diiron complex [Cp*(Ph2PC6H4S)Fe]2(μ-N2) (1) has been found to catalyze the hydroboration of N-heteroarenes with pinacolborane, giving N-borylated 1,2-reduced products with high regioselectivity. The catalysis is initiated by coordination… Click to show full abstract
A N2-bridged diiron complex [Cp*(Ph2PC6H4S)Fe]2(μ-N2) (1) has been found to catalyze the hydroboration of N-heteroarenes with pinacolborane, giving N-borylated 1,2-reduced products with high regioselectivity. The catalysis is initiated by coordination of N-heteroarenes to the iron center, while the B-H bond cleavage is the rate-determining step.
Keywords:
selective hydroboration;
catalyzed selective;
hydroboration heteroarenes;
heteroarenes iron;
iron catalyzed;
hydroboration
Journal Title: Journal of the American Chemical Society
Year Published: 2017
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Journal Title: Journal of the American Chemical Society
Year Published: 2017
Link to full text (if available)
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recommendations!