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Enantio- and diastereoselective conjunctive cross-coupling of β-substituted alkenylboron "ate" complexes is studied. Whereas β-substitution shifts the chemoselectivity of the catalytic reaction in favor of the Suzuki-Miyaura product, use of a… Click to show full abstract
Enantio- and diastereoselective conjunctive cross-coupling of β-substituted alkenylboron "ate" complexes is studied. Whereas β-substitution shifts the chemoselectivity of the catalytic reaction in favor of the Suzuki-Miyaura product, use of a boronic ester ligand derived from acenaphthoquinone allows the process to favor the conjunctive product, even with substituted substrates.
Keywords:
conjunctive cross;
enantioselective conjunctive;
diastereoselective enantioselective;
ligand;
cross coupling
Journal Title: Journal of the American Chemical Society
Year Published: 2018
Link to full text (if available)
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Journal Title: Journal of the American Chemical Society
Year Published: 2018
Link to full text (if available)
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recommendations!