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Quadruple Borylation of Terminal Alkynes.

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We present the first quadruple borylation reaction of terminal alkynes, affording functionalized 1,1,2,2-tetrakis(boronate) derivatives in a chemo-/regioselective manner. The methodology is operationally simple and a novel B-B bond activation without… Click to show full abstract

We present the first quadruple borylation reaction of terminal alkynes, affording functionalized 1,1,2,2-tetrakis(boronate) derivatives in a chemo-/regioselective manner. The methodology is operationally simple and a novel B-B bond activation without the need for a transition-metal catalyst.

Keywords: methodology; borylation terminal; quadruple borylation; terminal alkynes

Journal Title: Journal of the American Chemical Society
Year Published: 2019

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