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The first earth-abundant cobalt-catalyzed highly branched- and enantioselective allylic amination of racemic branched allylic car-bonates bearing alkyl groups with both aromatic and aliphatic amines have been developed. The process allows… Click to show full abstract
The first earth-abundant cobalt-catalyzed highly branched- and enantioselective allylic amination of racemic branched allylic car-bonates bearing alkyl groups with both aromatic and aliphatic amines have been developed. The process allows rapid access of allylic amines in high yields with exclusively branched selectivity and excellent enantioselectivities (normally 99% ee) under mild reaction conditions.
Keywords:
catalyzed regio;
enantioselective allylic;
allylic amination;
cobalt catalyzed
Journal Title: Journal of the American Chemical Society
Year Published: 2019
Link to full text (if available)
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Journal Title: Journal of the American Chemical Society
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!