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A synthesis of chiral hydrocarbons having C1 axis and C3 symmetry, which owe their chirality due to asymmetrical distribution of 12C/13C isotopes, is reported. Their absolute configurations assigned using the… Click to show full abstract
A synthesis of chiral hydrocarbons having C1 axis and C3 symmetry, which owe their chirality due to asymmetrical distribution of 12C/13C isotopes, is reported. Their absolute configurations assigned using the vibrational circular dichroism (VCD) technique conform with those deduced from the absolute configurations of the parent α-formyl cyclopropanes.
Keywords:
12c 13c;
synthesis stereochemical;
stereochemical assignment;
asymmetric synthesis;
assignment 12c;
synthesis
Journal Title: Journal of the American Chemical Society
Year Published: 2019
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Journal Title: Journal of the American Chemical Society
Year Published: 2019
Link to full text (if available)
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recommendations!