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This manuscript reports a visible light-mediated organosul-fide catalysis that enables the decarboxylative coupling between simple aliphatic alcohol and tertiary or secondary alkyl carboxylic acid-derived redox active esters to produce a… Click to show full abstract
This manuscript reports a visible light-mediated organosul-fide catalysis that enables the decarboxylative coupling between simple aliphatic alcohol and tertiary or secondary alkyl carboxylic acid-derived redox active esters to produce a C(sp3)-O-C(sp3) fragment. Results of the coupling using other heteroatom nucleophiles such as water, amides and thiols are also described.
Keywords:
bond formation;
catalyzed decarboxylative;
organophotoredox catalyzed;
decarboxylative sp3;
sp3 bond
Journal Title: Journal of the American Chemical Society
Year Published: 2020
Link to full text (if available)
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Journal Title: Journal of the American Chemical Society
Year Published: 2020
Link to full text (if available)
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recommendations!