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Predicting Rearrangement-Competent Terpenoid Oxidation Levels.

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Results of density functional calculations on rearrangements of potential biosynthetic precursors to the sesquiterpenoid illisimonin A reveal that only some possible precursors, those with certain specific oxidation patterns, are rearrangement-competent. Click to show full abstract

Results of density functional calculations on rearrangements of potential biosynthetic precursors to the sesquiterpenoid illisimonin A reveal that only some possible precursors, those with certain specific oxidation patterns, are rearrangement-competent.

Keywords: oxidation; predicting rearrangement; terpenoid oxidation; oxidation levels; rearrangement competent; competent terpenoid

Journal Title: Journal of the American Chemical Society
Year Published: 2020

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