LAUSR

Ultrahigh‐resolution air quality models that resolve sharp gradients of pollutant concentrations benefit the assessment of human health impacts. Mitigating fine particulate matter (PM2.5) concentrations over the past decade has triggered ozone (O3) deterioration in China. Effective control of both pollutants remains poorly understood from an ultrahigh‐resolution perspective. We propose a regional‐to‐local model suitable for quantitatively mitigating pollution pathways at various resolutions. Sensitivity scenarios for controlling nitrogen oxide (NOx) and volatile organic compound (VOC) emissions are explored, focusing on traffic and industrial sectors. The results show that concurrent controls on both sectors lead to reductions of 17%, 5%, and 47% in NOx, PM2.5, and VOC emissions, respectively. The reduced traffic scenario leads to reduced NO2 and PM2.5 but increased O3 concentrations in urban areas. Guangzhou is located in a VOC‐limited O3 formation regime, and traffic is a key factor in controlling NOx and O3. The reduced industrial VOC scenario leads to reduced O3 concentrations throughout the mitigation domain. The maximum decrease in median hourly NO2 is >11 μg/m³, and the maximum increase in the median daily maximum 8‐hr rolling O3 is >10 μg/m³ for the reduced traffic scenario. When controls on both sectors are applied, the O3 increase reduces to <7 μg/m³. The daily averaged PM2.5 decreases by <2 μg/m³ for the reduced traffic scenario and varies little for the reduced industrial VOC scenario. An O3 episode analysis of the dual‐control scenario leads to O3 decreases of up to 15 μg/m³ (8‐hr metric) and 25 μg/m³ (1‐hr metric) in rural areas.