An infinite number of crystal structures in a multicomponent alloy with a specific atomic ratio can be devised, although only thermodynamically-stable phases can be formed. Here, we experimentally show the… Click to show full abstract
An infinite number of crystal structures in a multicomponent alloy with a specific atomic ratio can be devised, although only thermodynamically-stable phases can be formed. Here, we experimentally show the first example of a layer-structured pseudo-binary alloy, theoretically called Z 3-FePd 3 . This Z 3 structure is achieved by adding a small amount of In, which is immiscible with Fe but miscible with Pd and consists of an alternate L 1 0 (CuAu-type)-PdFePd trilayer and Pd–In ordered alloy monolayer along the c axis. First-principles calculations strongly support that the specific inter-element miscibility of In atoms stabilizes the thermodynamically-unstable Z 3-FePd 3 phase without significantly changing the original density of states of the Z 3-FePd 3 phase. Our results demonstrate that the specific inter-element miscibility can switch stable structures and manipulate the material nature with a slight composition change. Synthetic routes of stabilizing crystal structures can discover atomic pickings with desired properties. Here the authors demonstrate inter-element miscibility of In can act as a stabilizer to create Z3-based ordered alloy without significantly changing the original density of state of Z3-FePd3.
               
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