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Growth of single-crystalline Bi2Te3 hexagonal nanoplates with and without single nanopores during temperature-controlled solvothermal synthesis

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Bismuth telluride (Bi2Te3) is a promising thermoelectric material for applications near room temperature. To increase the thermoelectric performance of this material, its dimensions and thermal transport should be decreased. Two-dimensional… Click to show full abstract

Bismuth telluride (Bi2Te3) is a promising thermoelectric material for applications near room temperature. To increase the thermoelectric performance of this material, its dimensions and thermal transport should be decreased. Two-dimensional nanoplates with nanopores are an ideal structure because thermal transport is disrupted by nanopores. We prepared Bi2Te3 nanoplates with single nanopores by a solvothermal synthesis and investigated their structural and crystallographic properties. The nanoplates synthesized at a lower reaction temperature (190 °C) developed single nanopores (approximately 20 nm in diameter), whereas the nanoplates synthesized at a higher reaction temperature (200 °C) did not have nanopores. A crystal growth mechanism is proposed based on the experimental observations.

Keywords: single nanopores; temperature; growth single; solvothermal synthesis

Journal Title: Scientific Reports
Year Published: 2019

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