LAUSR

Water and its interactions with metals are closely bound up with human life, and the reactivity of metal clusters with water is of fundamental importance for the understanding of hydrogen generation. Here a prominent hydrogen evolution reaction (HER) of single water molecule on vanadium clusters V n + (3 ≤  n  ≤ 30) is observed in the reaction of cationic vanadium clusters with water at room temperature. The combined experimental and theoretical studies reveal that the wagging vibrations of a V-OH group give rise to readily formed V-O-V intermediate states on V n + ( n  ≥ 3) clusters and allow the terminal hydrogen to interact with an adsorbed hydrogen atom, enabling hydrogen release. The presence of three metal atoms reduces the energy barrier of the rate-determining step, giving rise to an effective production of hydrogen from single water molecules. This mechanism differs from dissociative chemisorption of multiple water molecules on aluminium cluster anions, which usually proceeds by dissociative chemisorption of at least two water molecules at multiple surface sites followed by a recombination of the adsorbed hydrogen atoms. Metal clusters are known to catalyze hydrogen evolution from water, but reaction mechanisms and reactivities are still not fully understood. Here, mass spectrometry of cationic vanadium clusters reacting with water vapor shows significant hydrogen evolution reactions for V 3 + , V 5 + and V 9 + that point to a hydrogen release mechanism from the transition metal cluster cations.