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Occurrence of photoinduced charge separation by the modulation of the electronic coupling between pyrene dimers and chemically converted graphenes.

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The photoexcitation of the pyrene dimer on graphene resulted in the final formation of a charge-separated state following an exciplex formation, while that of the pyrene monomer on graphene generated… Click to show full abstract

The photoexcitation of the pyrene dimer on graphene resulted in the final formation of a charge-separated state following an exciplex formation, while that of the pyrene monomer on graphene generated the corresponding exciplex solely due to the difference in the electronic coupling between the pyrene and the graphene.

Keywords: photoinduced charge; occurrence photoinduced; electronic coupling; coupling pyrene; pyrene

Journal Title: Chemical communications
Year Published: 2017

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