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A five-fold interpenetrated metal-organic framework showing a large variation in thermal expansion behaviour owing to dramatic structural transformation upon dehydration-rehydration.

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A five-fold interpenetrated metal organic framework (MOF) has been shown to exhibit anomalous thermal expansion due to the combined effect of hinge-like motion and sliding of individual diamondoid networks. Upon… Click to show full abstract

A five-fold interpenetrated metal organic framework (MOF) has been shown to exhibit anomalous thermal expansion due to the combined effect of hinge-like motion and sliding of individual diamondoid networks. Upon dehydration, the MOF undergoes dramatic structural changes, thereby altering its thermal expansion behaviour to a large extent.

Keywords: interpenetrated metal; expansion; metal organic; five fold; fold interpenetrated; thermal expansion

Journal Title: Chemical communications
Year Published: 2017

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