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Highly efficient hydrolysis of ammonia borane by anion (-OH, F-, Cl-)-tuned interactions between reactant molecules and CoP nanoparticles.

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The CoP nanoparticle catalyst had excellent catalytic activity and a short catalytic induction period in the presence of anions, and high sustainability in ammonia borane hydrolysis, with an initial turnover… Click to show full abstract

The CoP nanoparticle catalyst had excellent catalytic activity and a short catalytic induction period in the presence of anions, and high sustainability in ammonia borane hydrolysis, with an initial turnover frequency of 72.2 mol(H2) mol(CoP)-1 min-1 at ambient temperature. This value is unprecedented for noble-metal-free catalytic systems.

Keywords: hydrolysis ammonia; borane; ammonia borane; efficient hydrolysis; highly efficient

Journal Title: Chemical communications
Year Published: 2017

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