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Palladium-catalyzed heteroannulation of [60]fullerene with phenols has been developed as a practical and efficient protocol for the one-pot synthesis of various [60]fullerene-fused benzofurans. A possible reaction mechanism is proposed to… Click to show full abstract
Palladium-catalyzed heteroannulation of [60]fullerene with phenols has been developed as a practical and efficient protocol for the one-pot synthesis of various [60]fullerene-fused benzofurans. A possible reaction mechanism is proposed to explain the formation of C60-fused benzofurans. A novel 1,2,3,16-adduct is obtained through further reaction of the electrochemically generated dianionic fullerobenzofuran with benzyl bromide.
Keywords:
fused benzofurans;
fullerene fused;
fullerene;
heteroannulation;
palladium catalyzed;
synthesis
Journal Title: Chemical communications
Year Published: 2017
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!