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Achieving red/near-infrared mechanoresponsive luminescence turn-on: mechanically disturbed metastable nanostructures in organic solids.

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Two slightly twisted A-π-D-π-A molecules were prepared to demonstrate that the red/near-infrared mechanoresponsive luminescence turn-on behaviors could be realized through mechanically disturbing their weakly/non-emissive metastable nanostructures, giving emissive amorphous aggregates… Click to show full abstract

Two slightly twisted A-π-D-π-A molecules were prepared to demonstrate that the red/near-infrared mechanoresponsive luminescence turn-on behaviors could be realized through mechanically disturbing their weakly/non-emissive metastable nanostructures, giving emissive amorphous aggregates with λem = 620 nm, ΦF = 12% (h-DIPT) and λem = 700 nm, ΦF = 10% (DIPT), respectively.

Keywords: red near; metastable nanostructures; near infrared; mechanoresponsive luminescence; luminescence turn; infrared mechanoresponsive

Journal Title: Chemical communications
Year Published: 2017

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