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Tris(S,S-dioxide)-trithiasumanene: strong fluorescence and cocrystal with 1,2,6,7,10,11-hexabutoxytriphenylene.

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Thiophene rings in trithiasumanene (1) are oxidized regioselectively to form tris(S,S-dioxide)-trithiasumanene (3). Compound 3 displays strong indigo fluorescence in both solution and the solid state, and forms a 1 : 1 cocrystal… Click to show full abstract

Thiophene rings in trithiasumanene (1) are oxidized regioselectively to form tris(S,S-dioxide)-trithiasumanene (3). Compound 3 displays strong indigo fluorescence in both solution and the solid state, and forms a 1 : 1 cocrystal with HBT to give a yellow emission in crystalline form.

Keywords: strong fluorescence; trithiasumanene strong; tris dioxide; dioxide trithiasumanene

Journal Title: Chemical communications
Year Published: 2017

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