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Strontium cobalt oxychlorides: enhanced electrocatalysts for oxygen reduction and evolution reactions.

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Cobalt-based layered perovskite oxychlorides Sr2CoO3Cl and Sr3Co2O5Cl2 exhibit high oxygen electrocatalytic activity compared to conventional lanthanum cobalt-based perovskite oxides. The enhanced oxygen electrocatalytic activity can be attributed to the upshifted… Click to show full abstract

Cobalt-based layered perovskite oxychlorides Sr2CoO3Cl and Sr3Co2O5Cl2 exhibit high oxygen electrocatalytic activity compared to conventional lanthanum cobalt-based perovskite oxides. The enhanced oxygen electrocatalytic activity can be attributed to the upshifted O p-band center relative to the Fermi level caused by the incorporation of chloride anion into oxygen sites.

Keywords: oxygen; cobalt; strontium cobalt; enhanced electrocatalysts; cobalt oxychlorides; oxychlorides enhanced

Journal Title: Chemical communications
Year Published: 2017

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