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Trinuclear versus dinuclear heterodimetallic UVO2+Co2+ complexes were selectively assembled via a cation-cation interaction by tuning the ligand. The trimeric complex 2, with a linear [Co-O[double bond, length as m-dash]U[double bond,… Click to show full abstract
Trinuclear versus dinuclear heterodimetallic UVO2+Co2+ complexes were selectively assembled via a cation-cation interaction by tuning the ligand. The trimeric complex 2, with a linear [Co-O[double bond, length as m-dash]U[double bond, length as m-dash]O-Co] core, exhibits magnetic exchange and slow relaxation with a reversal barrier of 30.5 ± 0.9 K providing the first example of a U-Co exchange-coupled SMM.
Keywords:
cation;
synthesis smm;
versus dinuclear;
trinuclear versus;
cation cation
Journal Title: Dalton transactions
Year Published: 2017
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!