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Ru/ceria-catalyzed direct formylation of amines and CO to produce formamides

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We herein report a new strategy of directly converting amines and CO to formamides with 100% atom utilization efficiency. It is suitable for up to 25 amine substrates with no… Click to show full abstract

We herein report a new strategy of directly converting amines and CO to formamides with 100% atom utilization efficiency. It is suitable for up to 25 amine substrates with no additives. Ru/ceria is found to be an excellent catalyst for this reaction due the efficient co-activation of CO and amine on Ru species.

Keywords: ceria catalyzed; formylation amines; produce formamides; catalyzed direct; direct formylation; amines produce

Journal Title: Green Chemistry
Year Published: 2017

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