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The Ndiazo,C3-diradical of diazomethane (˙NN–H2C˙) is a resonance structure with 1,3-dipole form. And alkyl diazoacetate (ethyl diazoacetate, EDA) can interact with α,β-unsaturated aldehyde (cinnamaldehyde, CA) without any catalyst to compose… Click to show full abstract
The Ndiazo,C3-diradical of diazomethane (˙NN–H2C˙) is a resonance structure with 1,3-dipole form. And alkyl diazoacetate (ethyl diazoacetate, EDA) can interact with α,β-unsaturated aldehyde (cinnamaldehyde, CA) without any catalyst to compose the Ndiazo,C5- and Ndiazo,C8-diradicals, which are the building species to produce the copolymer of EDA with CA through a sequential series of Ndiazo,Cω-diradical intermediates.
Keywords:
cinnamaldehyde;
copolymerization ethyl;
diazoacetate;
studies copolymerization;
mechanistic studies;
ethyl diazoacetate
Journal Title: Polymer Chemistry
Year Published: 2017
Link to full text (if available)
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Journal Title: Polymer Chemistry
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!