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A 3D metal–organic framework built from vanadate clusters and diamond chains showing weak ferromagnetic single-chain-magnet like behavior

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Magnetically weakly coupled diamond chains in the 3D metal–organic framework are well separated by diamagnetic [V4O12]4− cluster units and semi-rigid ligands, and exhibit not only weak ferromagnetic interactions with frustrated… Click to show full abstract

Magnetically weakly coupled diamond chains in the 3D metal–organic framework are well separated by diamagnetic [V4O12]4− cluster units and semi-rigid ligands, and exhibit not only weak ferromagnetic interactions with frustrated spin canting but also single-chain magnets with slow magnetic relaxation below 3.4 K.

Keywords: diamond chains; single chain; weak ferromagnetic; metal organic; organic framework

Journal Title: Journal of Materials Chemistry C
Year Published: 2017

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