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Gold-catalyzed ring-expansion through acyl migration to afford furan-fused polycyclic compounds.

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A gold-catalyzed ring-expansion reaction of alkynones to access furan-fused polycyclic compounds is reported. Mechanistic studies revealed that the reaction might occur through a tandem 1,2-acyl migration/Friedel-Crafts reaction. Click to show full abstract

A gold-catalyzed ring-expansion reaction of alkynones to access furan-fused polycyclic compounds is reported. Mechanistic studies revealed that the reaction might occur through a tandem 1,2-acyl migration/Friedel-Crafts reaction.

Keywords: ring expansion; furan fused; polycyclic compounds; fused polycyclic; catalyzed ring; gold catalyzed

Journal Title: Chemical communications
Year Published: 2017

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