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An achiral organic molecule adopts a chiral conformation, crystallizing in two morphologies: a racemic form, stable 90% of the time from the melt. Click to show full abstract
An achiral organic molecule adopts a chiral conformation, crystallizing in two morphologies: a racemic form, stable <70 °C, and a homochiral form, stable ≥70 °C. Upon seeding, crystal-to-crystal phase transitions occur reversibly between the racemic and chiral forms. Liquid-to-solid chiral crystallization is observed >90% of the time from the melt.
Keywords:
crystal crystal;
reversible crystal;
resolution making;
chiral resolution;
making breaking;
crystal chiral
Journal Title: Chemical communications
Year Published: 2017
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!