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De novo endo-functionalized organic cages as cooperative multi-hydrogen-bond-donating catalysts.

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Two endo-functionalized organic cages as oxyanion hole mimics were achieved via dynamic covalent chemistry, which exhibit good size selectivity, catalytic activity and broad substrate scopes for Friedel-Crafts reactions. The modular… Click to show full abstract

Two endo-functionalized organic cages as oxyanion hole mimics were achieved via dynamic covalent chemistry, which exhibit good size selectivity, catalytic activity and broad substrate scopes for Friedel-Crafts reactions. The modular character of the synthesis provides an easy way to modify the size, shape and inner function of the molecular cavity.

Keywords: cages cooperative; functionalized organic; cooperative multi; organic cages; novo endo; endo functionalized

Journal Title: Chemical communications
Year Published: 2017

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