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Aryl homocoupling reactions via meta- and ortho-selective C-H activation have been achieved on surfaces, but the highly important para-selective C-H activation has not been reported yet. Combined with scanning tunneling… Click to show full abstract
Aryl homocoupling reactions via meta- and ortho-selective C-H activation have been achieved on surfaces, but the highly important para-selective C-H activation has not been reported yet. Combined with scanning tunneling microscopy, time-of-flight secondary ion mass spectrometry and density functional theory, here we describe dehydrogenative homocoupling of tetrafluorobenzene on Pd(111) via para-selective C-H activation to form perfluorinated oligo(p-phenylene)s.
Keywords:
selective activation;
homocoupling tetrafluorobenzene;
para selective;
dehydrogenative homocoupling;
activation
Journal Title: Chemical communications
Year Published: 2017
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!