Ir-Catalyzed -COOH directed site-selective B-H/C-H dehydrogenative cross-coupling of o-carborane with thiophenes has been achieved for the first time. Without any pre-functionalization, carboranyl carboxylic acids and thiophenes can serve as suitable… Click to show full abstract
Ir-Catalyzed -COOH directed site-selective B-H/C-H dehydrogenative cross-coupling of o-carborane with thiophenes has been achieved for the first time. Without any pre-functionalization, carboranyl carboxylic acids and thiophenes can serve as suitable coupling partners, resulting in the preparation of 4-thienyl-o-carboranes in a simple one-pot process for potential applications in materials.
Keywords:
dehydrogenative cross;
carborane thiophenes;
cross coupling;
coupling carborane
Journal Title: Chemical communications
Year Published: 2017
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Journal Title: Chemical communications
Year Published: 2017
Link to full text (if available)
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recommendations!