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The first circularly polarized luminescence of achiral Eu-containing polyoxometalates (POMs) was realized by electrostatic assembly with a diblock copolymer containing bulky chiral pendants, and was unexpectedly enhanced by NaCl. The… Click to show full abstract
The first circularly polarized luminescence of achiral Eu-containing polyoxometalates (POMs) was realized by electrostatic assembly with a diblock copolymer containing bulky chiral pendants, and was unexpectedly enhanced by NaCl. The induced chirality is attributed to static coupling causing chiral torsion of POMs and dynamic coupling between organic chiral chromophores and an Eu emission center.
Keywords:
circularly polarized;
induced salt;
polarized luminescence;
containing polyoxometalates;
achiral containing
Journal Title: Chemical communications
Year Published: 2017
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!