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Selective Au-C bond cleavage and arene-C-H activation in (C^N^C)Au(iii) pincer complexes are reversible, leading to a solvent-dependent proton shuttling process. The ether-free cleavage products are non-fluxional and show weak gold(iii)-arene… Click to show full abstract
Selective Au-C bond cleavage and arene-C-H activation in (C^N^C)Au(iii) pincer complexes are reversible, leading to a solvent-dependent proton shuttling process. The ether-free cleavage products are non-fluxional and show weak gold(iii)-arene interactions commensurate with intermediates postulated for CMD-type arene activation.
Keywords:
proton shuttling;
arene;
gold iii;
arene activation
Journal Title: Chemical communications
Year Published: 2017
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2017
Link to full text (if available)
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recommendations!