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Synthesis of well-defined pentagonally prismatic silver nanoparticles: role of bromide in (100) stabilization and facet preservation.

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We have demonstrated the effect of bromide for exclusive (100) stabilization that enabled the preparation of pentagonal prisms (AgPPNPs), a newly developed nanoscale shape. High-quality precursors and exact amount of… Click to show full abstract

We have demonstrated the effect of bromide for exclusive (100) stabilization that enabled the preparation of pentagonal prisms (AgPPNPs), a newly developed nanoscale shape. High-quality precursors and exact amount of bromide were necessary requirements for the precise length and faceting control. Bromide excess resulted in AgPPNP rounding, highlighting a delicate balance in faceting control and shape preservation.

Keywords: stabilization; synthesis well; well defined; preservation; 100 stabilization; defined pentagonally

Journal Title: Chemical communications
Year Published: 2017

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