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Concise synthesis of oxacyclic compounds using highly discriminative two-way transformations of α,β-unsaturated esters in the presence of enones.

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Highly discriminative transformation of α,β-unsaturated esters in the presence of enones using two types of phosphonium salts, and their application to the synthesis of oxacyclic compounds in six steps in… Click to show full abstract

Highly discriminative transformation of α,β-unsaturated esters in the presence of enones using two types of phosphonium salts, and their application to the synthesis of oxacyclic compounds in six steps in one pot have been achieved.

Keywords: oxacyclic compounds; unsaturated esters; highly discriminative; synthesis oxacyclic; esters presence; presence enones

Journal Title: Chemical communications
Year Published: 2017

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