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Monoradical-containing four-coordinate Co(iii) complexes: homolytic S-S and Se-Se bond cleavage and catalytic isocyanate to urea conversion under sunlight.

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Four-coordinate, monoradical-containing Co(iii) complexes participated in the non-innocent ligand driven homolytic cleavage of S-S and Se-Se bonds and catalyzed the conversion of RNCO (R = phenyl and naphthyl) to the… Click to show full abstract

Four-coordinate, monoradical-containing Co(iii) complexes participated in the non-innocent ligand driven homolytic cleavage of S-S and Se-Se bonds and catalyzed the conversion of RNCO (R = phenyl and naphthyl) to the corresponding urea derivatives (TON 480) in dry CH2Cl2 under sunlight stimulus.

Keywords: monoradical containing; iii complexes; four coordinate; cleavage

Journal Title: Chemical communications
Year Published: 2017

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