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Facile access to unsymmetrically substituted tellurium-boron based heterocycles.

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Reactions of Te-B heterocycles Te((Ph)C[double bond, length as m-dash]C(C6F5))2B(C6F5) 1 with alcohols is shown to afford species of the form Te((Ph)C[double bond, length as m-dash]C(C6F5))2BOR. The subsequent reaction with either… Click to show full abstract

Reactions of Te-B heterocycles Te((Ph)C[double bond, length as m-dash]C(C6F5))2B(C6F5) 1 with alcohols is shown to afford species of the form Te((Ph)C[double bond, length as m-dash]C(C6F5))2BOR. The subsequent reaction with either 4-Br-C6H4CCH or 3-(C4H3S)CCH proceeds with the liberation of C6F5CCPh to give unsymmetrically substituted Te-B based heterocycles of the form Te((Ph)C[double bond, length as m-dash]C(C6F5))(HC[double bond, length as m-dash]CR)BOCH2Ph.

Keywords: length dash; based heterocycles; bond length; unsymmetrically substituted; double bond

Journal Title: Chemical communications
Year Published: 2017

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