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Scavenger templates: a systems chemistry approach to the synthesis of porphyrin-based molecular wires.

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A hexa-pyridyl template can be used as a scavenger to facilitate the synthesis of a linear porphyrin dodecamer from a mixture of linear hexamers with one or two terminal reactive… Click to show full abstract

A hexa-pyridyl template can be used as a scavenger to facilitate the synthesis of a linear porphyrin dodecamer from a mixture of linear hexamers with one or two terminal reactive groups. The template suppresses polymer formation by rapidly cyclizing the fully deprotected hexamer, thus up-regulating formation of the linear dodecamer.

Keywords: scavenger templates; chemistry; porphyrin; templates systems; systems chemistry; synthesis

Journal Title: Chemical communications
Year Published: 2017

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