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Strong circularly polarized luminescence induced from chiral supramolecular assembly of helical nanorods.

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Chiral supramolecular assemblies (BNS-BPP) can be self-assembled by electrostatic and π-π stacking interactions between the chiral binaphthyl sulphonate (BNS) anion and the achiral bipyrene-based pyridinium (BPP) cation chromophore. BNS-BPP can… Click to show full abstract

Chiral supramolecular assemblies (BNS-BPP) can be self-assembled by electrostatic and π-π stacking interactions between the chiral binaphthyl sulphonate (BNS) anion and the achiral bipyrene-based pyridinium (BPP) cation chromophore. BNS-BPP can exhibit strong CD and circularly polarized luminescence (CPL) signals, and the dissymmetry factor glum values can be up to 0.079.

Keywords: luminescence induced; chiral supramolecular; circularly polarized; polarized luminescence; strong circularly

Journal Title: Chemical communications
Year Published: 2017

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