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A new multitalented azine ligand: elastic bending, single-crystal-to-single-crystal transformation and a fluorescence turn-on Al(iii) sensor.

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We report a rare combination of two unique properties of an azine based ligand (H3L): in a solid-state crystalline material it shows highly flexible and elastic behavior which on triggering… Click to show full abstract

We report a rare combination of two unique properties of an azine based ligand (H3L): in a solid-state crystalline material it shows highly flexible and elastic behavior which on triggering with light results in slight deviation with phase transformation at the Single-Crystal-to-Single-Crystal (SCSC) level. Furthermore, in the solution state it acts as a highly selective, sensitive and reversible Al3+ sensor with a detection limit of 42 nM.

Keywords: crystal single; single crystal; new multitalented; transformation; crystal; ligand

Journal Title: Chemical communications
Year Published: 2017

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