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Direct alkylheteroarylation of alkenes via photoredox mediated C-H functionalization.

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The direct alkylheteroarylation of alkenes with cyclic and acyclic ethers via distal heteroaryl ipso-migration has been accomplished through the design of a photoredox-mediated C-H functionalization pathway. The use of inexpensive… Click to show full abstract

The direct alkylheteroarylation of alkenes with cyclic and acyclic ethers via distal heteroaryl ipso-migration has been accomplished through the design of a photoredox-mediated C-H functionalization pathway. The use of inexpensive ethers as radical precursors combined with a straightforward method makes this a practical approach.

Keywords: photoredox mediated; alkylheteroarylation alkenes; direct alkylheteroarylation; mediated functionalization

Journal Title: Chemical communications
Year Published: 2017

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