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Box-like gel capsules from heterostructures based on a core-shell MOF as a template of crystal crosslinking.

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New polymer capsules (PCs) were obtained using a crystal crosslinking (CC) method on core-shell MOF crystals. The latter are based on the epitaxial growth of two isostructural coordination polymers which… Click to show full abstract

New polymer capsules (PCs) were obtained using a crystal crosslinking (CC) method on core-shell MOF crystals. The latter are based on the epitaxial growth of two isostructural coordination polymers which are then selectively crosslinked. Decomposition of the non-reticulated phase leads to new PCs, possessing a well-defined hollow cubic shape reflecting the heterostructure of the template.

Keywords: crystal crosslinking; shell mof; core shell

Journal Title: Chemical communications
Year Published: 2018

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