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A pyrene-functionalized foldamer: structural impact and recognition properties supported by donor-acceptor interactions.

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An electroactive and luminescent foldamer based on an oligopyridine biscarboxamide skeleton was synthesized and characterised. Its conformation in the solid state proved to be strongly affected by the peripheral pyrene… Click to show full abstract

An electroactive and luminescent foldamer based on an oligopyridine biscarboxamide skeleton was synthesized and characterised. Its conformation in the solid state proved to be strongly affected by the peripheral pyrene units. The latter also endow the target derivative with recognition abilities toward electron-withdrawing molecules, which allow tuning of the spectroscopic properties of the foldamer.

Keywords: pyrene functionalized; recognition; functionalized foldamer; impact recognition; structural impact; foldamer structural

Journal Title: Chemical communications
Year Published: 2017

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