Photo from wikipedia
The first high molar mass polyaminoboranes with an organic substituent at boron, namely the B-arylated polyaminoboranes [NH2-BHPh]n (2a) and [NH2-BH(p-CF3C6H4)]n (2b), have been prepared via catalytic dehydropolymerisation. These materials can… Click to show full abstract
The first high molar mass polyaminoboranes with an organic substituent at boron, namely the B-arylated polyaminoboranes [NH2-BHPh]n (2a) and [NH2-BH(p-CF3C6H4)]n (2b), have been prepared via catalytic dehydropolymerisation. These materials can be considered as inorganic analogues of polystyrene with a B-N main chain. Their synthesis was achieved from B-aryl amine-borane precursors in solution using an [IrH2(POCOP)] precatalyst.
Keywords:
via catalytic;
analogues polystyrene;
main chain;
nitrogen main;
boron nitrogen
Journal Title: Chemical communications
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Chemical communications
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!