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H-Bonded anion-anion complex trapped in a squaramido-based receptor.

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Herein we report the experimental observation (X-ray characterization) of an anion-anion complex (anion = hydrogen fumarate) stabilized by H-bonds that is trapped in a secondary squaramide receptor. High level ab… Click to show full abstract

Herein we report the experimental observation (X-ray characterization) of an anion-anion complex (anion = hydrogen fumarate) stabilized by H-bonds that is trapped in a secondary squaramide receptor. High level ab initio calculations indicate that the anion-anion complex is thermodynamically unstable but kinetically stable with respect to the isolated anions.

Keywords: anion; anion anion; complex trapped; bonded anion; receptor; anion complex

Journal Title: Chemical communications
Year Published: 2018

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