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Nickel(ii) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction.

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The first example of a CNC pincer ligand with a central pyridinol ligand is reported in a nickel(ii) complex. This metal complex can be protonated or deprotonated reversibly in situ… Click to show full abstract

The first example of a CNC pincer ligand with a central pyridinol ligand is reported in a nickel(ii) complex. This metal complex can be protonated or deprotonated reversibly in situ to switch on or off the photocatalytic performance towards CO2 reduction. The O- substituent appears essential for catalysis.

Keywords: pincer; reduction; nickel pincer; complexes demonstrate; substituent; pincer complexes

Journal Title: Chemical communications
Year Published: 2018

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