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Task-specific design of a hierarchical porous aromatic framework as an ultrastable platform for large-sized catalytic active site binding.

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An amine-tagged hierarchical porous aromatic framework PAF70-NH2 with ultra-stability and narrowly distributed mesopores was synthesized. PAF70-NH2 has high potential for covalently immobilizing a relatively large-sized catalyst inside its pores. This… Click to show full abstract

An amine-tagged hierarchical porous aromatic framework PAF70-NH2 with ultra-stability and narrowly distributed mesopores was synthesized. PAF70-NH2 has high potential for covalently immobilizing a relatively large-sized catalyst inside its pores. This work gave a perfect example of using PAF70-NH2 as a platform for completely recyclable heterogeneous organocatalysis.

Keywords: aromatic framework; hierarchical porous; porous aromatic; platform; large sized

Journal Title: Chemical communications
Year Published: 2018

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