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Rational design of double-shelled Fe-, N-, and S-tridoped hollow mesoporous carbon spheres as high-performance catalysts for organic reactions.

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Herein, hollow large-pore mesoporous carbon spheres with double Fe-, N-, and S-tridoped shells (DSHM-Fe/SNC) were fabricated via a rational self-sacrificing template route. Benefiting from the abundance of multi-heteroatom doping induced… Click to show full abstract

Herein, hollow large-pore mesoporous carbon spheres with double Fe-, N-, and S-tridoped shells (DSHM-Fe/SNC) were fabricated via a rational self-sacrificing template route. Benefiting from the abundance of multi-heteroatom doping induced active sites, unique hierarchical structures to enhance active site exposure, and conductive networks to facilitate electron transfer, the as-prepared DSHM-Fe/SNC materials exhibit remarkable catalytic performance and excellent reusability toward reduction of p-nitrophenol.

Keywords: design double; carbon spheres; rational design; performance; mesoporous carbon

Journal Title: Chemical communications
Year Published: 2018

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