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Tailoring defects in metal–organic frameworks is important for enhancing sorption and reaction properties. Defects in UiO-66 have been characterized for the first time by using water adsorption measurements. We found… Click to show full abstract
Tailoring defects in metal–organic frameworks is important for enhancing sorption and reaction properties. Defects in UiO-66 have been characterized for the first time by using water adsorption measurements. We found that the defect-induced hydrophilicity, quantitatively expressed by the Henry constant and the saturation water uptake, correlates well with the catalytic performance in the cyanosilylation of benzaldehyde.
Keywords:
defects metal;
water;
chemistry;
metal organic;
using water;
water adsorption
Journal Title: CrystEngComm
Year Published: 2017
Link to full text (if available)
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Journal Title: CrystEngComm
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!