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The host H, 9,9′-(ethyne-1,2-diyl)-bis(fluoren-9-ol), forms inclusion compounds with a series of alcohols with similar boiling points and displays selectivity in the sequence 3-pentanol > 2-pentanol > 3-methyl-2-butanol > 1-butanol. The… Click to show full abstract
The host H, 9,9′-(ethyne-1,2-diyl)-bis(fluoren-9-ol), forms inclusion compounds with a series of alcohols with similar boiling points and displays selectivity in the sequence 3-pentanol > 2-pentanol > 3-methyl-2-butanol > 1-butanol. The structures of two polymorphic apohosts and the inclusion compounds formed with each alcohol have been elucidated. The thermal stability results agree with the selectivity results from competition experiments.
Keywords:
aliphatic alcohols;
chemistry;
selectivity aliphatic;
alcohols host;
selectivity
Journal Title: CrystEngComm
Year Published: 2017
Link to full text (if available)
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Journal Title: CrystEngComm
Year Published: 2017
Link to full text (if available)
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recommendations!