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Fluorescence-based detection of nitroaromatics using a luminescent second sphere adduct self-assembled by charge-assisted hydrogen bonds

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Using second sphere interactions (outer sphere) by means of charge-assisted hydrogen bonds, a new Cd luminescent metal organic material has been prepared and successfully applied to the detection of trace… Click to show full abstract

Using second sphere interactions (outer sphere) by means of charge-assisted hydrogen bonds, a new Cd luminescent metal organic material has been prepared and successfully applied to the detection of trace amounts of nitrobenzene, 2-nitrotoluene and 3-nitrotoluene. The luminescence properties of the Cd crystal display selectivity and sensitivity to nitrobenzene derivatives with a high quenching efficiency.

Keywords: detection; assisted hydrogen; hydrogen bonds; second sphere; charge assisted

Journal Title: CrystEngComm
Year Published: 2018

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