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Co–Co and Co–Fe cyano-bridged pentanuclear clusters based on a methylpyrazinyl-diamine tetradentate ligand: spin crossover and metal substitution effects

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A pentanuclear CoII–CoIII cluster complex has been developed by a solvothermal synthesis. Its highly stable metal-mixed iron–cobalt derivatives display robust spin crossover (T1/2 = 268 K) controlled by the degree… Click to show full abstract

A pentanuclear CoII–CoIII cluster complex has been developed by a solvothermal synthesis. Its highly stable metal-mixed iron–cobalt derivatives display robust spin crossover (T1/2 = 268 K) controlled by the degree of substitution.

Keywords: metal; cyano bridged; spin crossover; substitution

Journal Title: CrystEngComm
Year Published: 2017

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