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Growth mechanisms of fiber-like and dendrite-like boron in a Cu melt

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The morphology evolution and growth mechanisms of boron in a Cu melt have been studied in this work. It was found that there are two different morphologies of eutectic boron… Click to show full abstract

The morphology evolution and growth mechanisms of boron in a Cu melt have been studied in this work. It was found that there are two different morphologies of eutectic boron in a Cu melt at ambient pressure, i.e. fiber-like and dendrite-like. These two morphologies have different crystal structures and growth mechanisms. The fiber-like boron should be single crystal and has an alpha-tetragonal structure. The dendrite-like boron should have an alpha-rhombohedral structure, and twin growth facilitates its dendrite growth. The synthesis temperature is a factor that induces the morphology change of eutectic boron. In addition, boron nanowires can be prepared from the fiber-like eutectic boron by increasing the cooling rate of the Cu melt.

Keywords: growth mechanisms; dendrite like; boron melt; fiber like; boron; growth

Journal Title: CrystEngComm
Year Published: 2018

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