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Directed evolution of the periodic table: probing the electronic structure of late actinides.

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Recent investigations of the coordination chemistry and physical properties of berkelium (Z = 97) and californium (Z = 98) have revealed fundamental differences between post-curium elements and lighter members of… Click to show full abstract

Recent investigations of the coordination chemistry and physical properties of berkelium (Z = 97) and californium (Z = 98) have revealed fundamental differences between post-curium elements and lighter members of the actinide series. This review highlights these developments and chronicles key findings and concepts from the last half-century that have helped usher in a new understanding of the evolution of electronic structure in the periodic table.

Keywords: electronic structure; periodic table; directed evolution

Journal Title: Dalton transactions
Year Published: 2017

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